What have you tried? where are you stuck?

Most commands will be just same old w32tm / whatever you want to use.
You don’t want to sync from the new Domain Controller?

You can specify a custom NTP server in the reg key:

HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\Windows\CurrentVersion\DateTime\Servers

If you post code, please use the ‘Insert Code’ button. Please and thank you!

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